Ethene/alkyne exchange reaction at an intramolecular frustrated Lewis pair.
نویسندگان
چکیده
A vicinal ethylene bridged S/B frustrated Lewis pair (FLP) in situ generated by a hydroboration reaction of phenyl vinyl sulfide, reacts with p-tert-butylphenylacetylene by ethene/alkyne exchange and subsequent 1,2-addition of a second alkyne equivalent to give a zwitterionic sulfonium/borate product.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 50 16 شماره
صفحات -
تاریخ انتشار 2014